Ice floats because it is less dense than liquid water. When water freezes, its molecules form a crystal lattice structure that is more open and spacious, with more space between molecules compared to liquid water. This hexagonal arrangement caused by hydrogen bonding creates a solid ice structure that occupies more volume but has less density than the liquid form. Due to this lower density, ice is buoyant and floats on water according to Archimedes' principle, which states that an object will float if it is less dense than the fluid it displaces. This property is vital for aquatic ecosystems, as ice floats on the surface of lakes and oceans, insulating the water below and allowing life to survive underneath.